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991.
992.
An efficient one-pot method has been developed for the synthesis of α-oxycarbanilinophosphonates via a one-pot reaction of an aldehyde with diethyl phosphite in the presence of magnesium oxide followed by reaction with an isocyanate under solvent-free conditions using ultrasonic irradiation. This method is simple, rapid and good yielding. 相似文献
993.
Maryam Mirza‐Aghayan Rabah Boukherroub Mahshid Rahimifard Mohammad Bolourtchian 《应用有机金属化学》2010,24(6):477-480
Reduction of a variety of nitroaromatic compounds with triethylsilane in the presence of catalytic amounts of palladium chloride in ethanol resulted in the formation of the corresponding anilines in excellent yields. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
994.
995.
996.
A new rarely reported ZnII mixed‐polypyridine coordination polymer with both rigid and flexible spacers, {[Zn(bpp)2(μ‐4,4′‐bipy)(H2O)2](ClO4)2 · H2O}n ( 1 ), has been synthesized and characterized by elemental analysis, IR‐, 1H NMR‐, 13C NMR spectroscopy and single‐crystal X‐ray diffraction. The thermal stability of compound 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The single‐crystal X‐ray structure of 1 shows that the complex has been formed from a 1D polymer as a result of bridging by the 4,4′‐bipy ligands. Solution and solid‐state luminescent spectra of the compound 1 indicate intense fluorescent emissions at ca. 353.6 and 468.8 nm, respectively. Removal of the interstitial water guest molecules results in a loss of crystallinity, but exposure to water vapor reestablishes the original structure, thus constituting 1 as a third‐generation porous framework. 相似文献
997.
Maryam Shojaei Abdolreza Mirmohseni Yadollah Omidi Maryam Farbodi 《Applied biochemistry and biotechnology》2009,159(1):54-64
Homovanillic acid (HVA) and vanillylmandelic acid (VMA) were selectively determined by quartz crystal nanobalance sensor in
conjunction with net analyte signal (NAS)-based method called HLA/GO. An orthogonal design was applied for the formation of
calibration and prediction sets including HVA, VMA, and some common and structurally similar urine compounds. The selection
of the optimal time range involved the calculation of the NAS regression plot in any considered time window for each test
sample. The searching of a region with maximum linearity of NAS regression plot (minimum error indicator) and minimum of predicted
error sum of squares value was carried out by applying a moving window strategy. Based on the obtained results, the differences
on the adsorption profiles in the time range between 1 and 300 s were used to determine mixtures of compounds by HLA/GO method.
Several figures of merit like selectivity, sensitivity, analytical sensitivity, and limit of detection were calculated for
both compounds. The results showed that the method was successfully applied for the determination of VMA and HVA. 相似文献
998.
Maryam Bordbar Ali Yeganeh-Faal Jahanbakhsh Ghasemi Mohammad Mahdi Ahari-Mostafavi Nahid Sarlak Mohammad Taghi Baharifard 《Chemical Papers》2009,63(3):336-344
A simple, sensitive and selective spectrophotometric method for simultaneous determination of tretinoin and minoxidil using
partial least square (PLS) calibration and H-point standard addition method (HPSAM) is described. The results of the H-point
standard addition method show that minoxidil and tretinoin can be determined simultaneously with the concentration ratio of
tretinoin to minoxidil varying from 2: 1 to 1: 33 in mixed samples. A partial least squares multivariate calibration method
for the analysis of binary mixtures of tretinoin and minoxidil was also developed. The total relative standard error for applying
the PLS method to eleven synthetic samples in the concentration range of 0–10 μg mL−1 tretinoin and 0–32 μg mL−1 minoxidil was 2.59 %. Both proposed methods (PLS and HPSAM) were also successfully applied in the determination of tretinoin
and minoxidil in several synthetic pharmaceutical solutions. 相似文献
999.
Behrooz Khosravi 《Siberian Mathematical Journal》2009,50(2):355-359
Let G be a finite group. The prime graph of G is denoted by Γ(G). The main result we prove is as follows: If G is a finite group such that Γ(G) = Γ(L 10(2)) then G/O 2(G) is isomorphic to L 10(2). In fact we obtain the first example of a finite group with the connected prime graph which is quasirecognizable by its prime graph. As a consequence of this result we can give a new proof for the fact that the simple group L 10(2) is uniquely determined by the set of its element orders. 相似文献
1000.
A series of naphthalimide‐based alkali‐clearable azo disperse dyes containing a fluorosulfonyl group was synthesized. 4‐Fluorosulfonylaniline, 4‐fluorosulfonyl‐2‐nitroaniline and 6‐chloro‐4‐fluorosulfonyl‐2‐nitroaniline as the diazo components were prepared from N‐acetylsulfanilyl chloride and were subsequently coupled with 4‐hydroxy‐N‐3‐methoxypropyl‐1, 8‐naphthalimide. The synthesized dyes and their intermediates were characterized by the use of DSC, FTIR, 1H NMR, 13C NMR, Mass spectroscopy and UV‐visible spectroscopic techniques. Spectrophotometric investigations of prepared dyes in different solvents were carried out in order to obtain their absorption maxima, molar extinction coefficients and solvatochromic effects. The obtained dyes were applied to polyester fabric by the HT method and exhibited good leveling, wash and sublimation fastnesses and moderate light fastness. The synthesized dyes showed that incorporated fluorosulfonyl group to these dyes can be converted to the dyes containing a water soluble sulfonate group in the relatively mild alkaline conditions. 相似文献